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Vibrational spectra oftrans-dichlorodiiodoethylene

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Abstract

The infrared spectra oftrans-dichlorodiiodoethylene as a solid and in solution were recorded in the region 4000–25 cm−1. Raman spectra of the compound were obtained and semiquantitative polarization data were calculated.

The mutual exclusion between the infrared and Raman frequencies are in agreement with the expectedC 2h (2/m) symmetry for this molecule. The fundamentals have been assigned and a normal coordinate analysis carried out. Thermodynamic functions and the root mean square amplitudes of vibration have been obtained.

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Authors and Affiliations

  1. Department of Chemistry, University of Oslo, Oslo 3, Norway

    S. B. Lie & P. Klaboe

  2. Chemical Laboratory V, H.C. Ørsted Institute, Copenhagen, Denmark

    D. H. Christensen

  3. Institute of Theoretical Chemistry, Technical University of Norway, Trondheim, Norway

    G. Hagen

Authors
  1. S. B. Lie
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  2. P. Klaboe
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  3. D. H. Christensen
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  4. G. Hagen
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Additional information

The authors wish to acknowledge financial support from theNorwegian Research Council for Science and the Humanities.

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Lie, S.B., Klaboe, P., Christensen, D.H. et al. Vibrational spectra oftrans-dichlorodiiodoethylene. Journal of Crystal and Molecular Structure 1, 33–41 (1971). https://doi.org/10.1007/BF01200917

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  • DOI: https://doi.org/10.1007/BF01200917

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