Abstract
The author considers the results of calculations of the limiting values of the elastic properties (modulus of elasticity and load-extension diagram) of the main types of chemical fibers, using a model with "ideal orientation" of the molecules and the derived laws of deformation of polymer chains. A method is proposed for calculating the elastic properties of "ideally oriented" polymers from the velocity of propagation of an elastic deformation pulse and the effective density of the "skeletons" of the polymer chains. Values of the moduli of elasticity of the amorphous regions of the structure of oriented polymers are calculated. The calculated results are compared with experimental data on the elastic properties of fibers.
Similar content being viewed by others
References
H. Mark and W. Lothmar, Helv. chim. Acta, 19, 68, 1936.
L. C. G. Treloar, Polymer, 1, 95, 1960.
L. C. G. Treloar, Polymer, 1, 279, 290, 1960.
W. J. Lyons, J. Appl. Phys., 29, 1429, 1958.
W. J. Lyons, J. Appl. Phys., 30, 796, 1959.
T. Shimanouchi et al., J. Polym. Sci., 59, 93, 1962.
M. Asahina and S. Enomoto, J. Polym. Sci., 59, 101, 1962.
R. Miller and L. E. Nielsen, J. Polym. Sci., 44, 391, 1960; 55, 643, 1961.
A. I. Kitaigorodskii, Organic Crystallochemistry [in Russian], Izd-vo AN SSSR, 1955.
M. V. Vol'kenshtein, Structure and Physical Properties of Molecules [in Russian], Izd-vo AN SSSR, 1955.
M. V. Vol'kenshtein, Configuration Statistics of Polymer Chains [in Russian], Izd-vo AN SSSR, 1959.
Ya. K. Syrkin and M. E. Dyatkina, The Chemical Bond and the Structure of Molecules [in Russian], Goskhimizdat, 1947.
G. Herzberg, Spectra of Polyatomic Molecules [Russian translation], IL, 1949.
M. V. Vol'kenshtein, M. A. Elyashevich, and B. I. Stepanov, Molecular Vibrations [in Russian], Gostekhteorizdat, 1949.
S. Krimm, C. Liang, and G. Sutherland, J. Chem. Phys., 25, 549, 1956.
I. Sakurada et al., Chem. High. Polym. Japan, 19, 285, 292, 300, 1962; J. Polym. Sci., 57, 652, 1962.
W. I. Dolmage and C. E. Contois, J. Polym. Sci., 28, 275, 1958.
M. Korematsu et al., J. Soc. Text. Cell. Ind. Japan, 16, 388, 1960.
J. Mann and L. Roldan-Gonzalez, Polymer, 3, 549, 1962.
J. Sakurada et al., Chem. High. Polym. Japan, 21, 206, 1964.
V. A. Kargin and G. L. Slonimskii, Brief Outlines of the Physical Chemistry of Polymers [in Russian], Izd. MGU, 1960.
S. N. Zhurkov, A. I. Slutsker, and A. A. Yastrebinskii, FTT, 6, 3601, 1964.
R. Hosemann, Polymer, 3, 349, 1962.
N. V. Mikhailov, Khim. volokna, 1, 7, 1964.
E. M. Belavtseva, K. Z. Gumargalieva, and A. I. Kitaigorodskii, DAN, 151, 1356, 1963.
S. N. Zhurkov, A. I. Slutsker, and A. A. Yastrebinskii, DAN, 153, 303, 1963.
I. Sakurada, Khim. i tekhnol. polim., 10, 19, 1964.
B. S. Spaque and H. D. Noether, Text. Res. J., 31, 858, 1961.
K. E. Perepelkin, Khim. volokna (in the press).
K. E. Perepelkin, Investigation of the Mechanism of the Processes of Obtaining Fibers Based on Polyvinyl Alcohol. Dissertation Kirov LITLP, 1965.
Author information
Authors and Affiliations
Additional information
Mekhanika Polimerov, Vol. 2, No. 1, pp. 34–42, 1966
Paper read at the XIV All-Union Conference on High-Molecular Compounds, Oriented State.
Rights and permissions
About this article
Cite this article
Perepelkin, K.E. Some laws of the elastic properties of oriented fibrous polymers and fibers. Polymer Mechanics 2, 21–26 (1966). https://doi.org/10.1007/BF01198438
Issue Date:
DOI: https://doi.org/10.1007/BF01198438