Summary
The conditions fox coulometric determination of small quantities of hydrazine, phenylhydrazine and isoniazid in glacial acetic acid with electrogenerated manganese(III) acetate and lead(IV) acetate were investigated. With the direct coulometric method at room temperature, good results were obtained in the determination of hydrazine and isoniazid with lead(IV) acetate and in the determination of phenylhydrazine with manganese(III) acetate. Hydrazine and isoniazid can also be determined by the coulometric back-titration method if the oxidation with manganese(III) acetate is performed at elevated temperature.
Zusammenfassung
Die Bedingungen für die coulometrische Bestimmung kleiner Mengen Hydrazin, Phenylhydrazin und Isoniazid mit elektrolytisch erzeugtem Mangan(III)-Acetat und Blei(IV)-Acetat in Eisessig wurden untersucht. Bei Zimmertemperatur wurden gute Resultate durch direkte coulometrische Titration des Hydrazins und Isoniazids mit Blei(IV)-Acetat und bei Titration des Phenylhydrazins mit Mangan(III)-Acetat erhalten. Durch coulometrische Rücktitration können bei höheren Temperaturen Hydrazin und Isoniazid mit Mangan(III)-Acetat erfolgreich bestimmt werden.
Similar content being viewed by others
References
W. C. Bray and E. J. Cuy, J. Amer. Chem. Soc.46, 858 (1924).
I. M. Kolthoff, J. Amer. Chem. Soc.46, 2009 (1924).
R. A. Penneman and L. F. Audrieth, Analyt. Chemistry20, 1058 (1948).
B. R. Sant, Analyt. Chim. Acta20, 371 (1959).
E. J. Cuy and W. C. Bray, J. Amer. Chem. Soc.46, 1786 (1924).
H. T. S. Britton and M. Königstein, J. Chem. Soc.1940, 673.
M. G. Bapat and B. Sharma, Z. analyt. Chem.157, 258 (1957).
A. Kurtenacker and J. Wagner, Z. anorg. allg. Chem.120, 261 (1922).
Z. Szebellédy and Z. Somogyi, Z. analyt. Chem.112, 391 (1938).
M. S. Jovanović, D. J. Gaberšček, S. M. Veskovič, and M. V. Veljkovič, Bull. soc. chim. Beograd,25–26, 549 (1960–1961).
L. Rosenthaler, Pharm. Acta Helv.30, 69 (1955).
E. C. Olson, Analyt. Chemistry32, 1545 (1960).
P. Endroi, Magy. Kém. Folyóirat59, 211 (1953).
C. O. Miller and H. N. Furman, J. Amer. Chem. Soc.59, 161 (1937).
H. T. S. Britton and M. E. Clissold, J. Chem. Soc.1942, 528.
T. Canbäck, J. Pharm. Pharmacol.4, 407 (1952).
E. A. Haugas and B. W. Mitchell, J. Pharm. Pharmacol.4, 687 (1952).
A. F. Krivis, E. S. Gazda, G. R. Supp, and P. Kippur, Analyt. Chemistry35, 1955 (1963).
V. J. Jennings, A. Dodson, and A. Harrison, Analyst99, 145 (1974).
J. Vulterin and J. Zýka, Talanta10, 891 (1963).
A. P. Domleo, J. Pharm. Pharmacol.5, 117 (1953).
A. Berka and J. Zýka, Coll. Czechoslov. Chemic. Commun.24, 105 (1959).
T. J. Pastor, V. J. Vajgand, and Z. Kićović, Mikrochim. Acta [Wien]1976 II, 525.
P. K. Agasyan and M. A. Sirakanyan, Zh. Analit. Khim.26, 992 (1971).
E. J. Cuy, M. E. Rosenberg, and W. C. Bray, J. Amer. Chem. Soc.46, 1796 (1924).
W. C. E. Higginson, D. Sutton, and P. Wright, J. Chem. Soc.1953, 1380.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pastor, T.J., Vajgand, V.J. & Antonijević, V.V. Coulometric redox titrations of hydrazine, phenylhydrazine and isoniazid with electrogenerated lead(IV) acetate and manganese(III) acetate in acetic acid. Mikrochim Acta 70, 131–139 (1978). https://doi.org/10.1007/BF01196475
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01196475