Skip to main content
SpringerLink
Log in

Radioactive tracer study of adsorption and exchange reaction of lead ion selective electrode membrane

Radiochemische Untersuchung der Adsorptions- und Austauschreaktionen bleiionenspezifischer Elektroden

  • Published:
Microchimica Acta Aims and scope Submit manuscript

Summary

The amount of adsorption and exchange of lead on the electrode membrane as a function of time was correlated to the potential measurement stability. The adsorption and exchange of lead in various organic solvents tend to be increased relating to the increase in the dielectric constant of solvents. Removal of O2 and CO2 and addition of methanol and formaldehyde are very effective means to improve the potential stability. The behavior of lead ISE exposed to solutions containing lead and other interfering ions was also studied.

Zusammenfassung

Adsorption und Austausch von Blei an der Elektrodenmembran als Funktion der Zeit wurden zur Stabilität der Potentialmessung in Beziehung gesetzt. In verschiedenen organischen Lösungsmitteln steigen Adsorption und Austausch mit der Dielektrizitätskonstante an. Die Entfernung von O2 und CO2 sowie der Zusatz von Methanol und Formaldehyd verbessern die Stabilität des Potentials. Das Verhalten von bleiionenspezifischen Elektroden gegenüber Lösungen, die Blei und andere störende Ionen enthalten, wurde untersucht.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. J. M. Heijne, W. E. van der Linden, and G. Den Boef, Analyt. Chim. Acta100, 193 (1978).

    Google Scholar 

  2. G. J. M. Heijne and W. E. van der Linden, Analyt. Chim. Acta93, 99 (1977).

    Google Scholar 

  3. A. S. Manocha and R. L. Park, Applications of Surface Science1, 129 (1977).

    Google Scholar 

  4. D. S. Zingg and D. M. Hercules, J. Phys. Chem.82 (18), 1992 (1978).

    Google Scholar 

  5. H. R. Skewes, Proc. Austr. Int. Min. Mit. No. 244, Dec. 1972.

  6. G. Carmak and H. Freiser, US. NTIS, AD-A, 1975, No. 008236, p. 24.

  7. A. Campiglio, Mikrochim. Acta [Wien]1979 I, 267.

    Google Scholar 

  8. J. W. Schultze, P. Kohl, M. Lohrengel, and U. Stimming, Chem. Ing. Tech.51 (6), 643 (1979).

    Google Scholar 

  9. D. Midgley, Analyt. Chim. Acta87, 19 (1976).

    Google Scholar 

  10. Y. S. Khvorostin, M. S. Shikanova, I. G. Raskina, T. A. Robers, and E. A. Ivanova, Zh. Anal. Khim.34, 1694 (1979).

    Google Scholar 

  11. T. B. Grimley, Proc. Roy. Soc. A201, 40 (1950).

    Google Scholar 

  12. J. Koryta, Ion Selective Electrodes, London: Willium Clowes. 1975.

    Google Scholar 

  13. N. Hackerman and S. J. Stephens, J. Phys. Chem.58, 904 (1954).

    Google Scholar 

  14. B. E. Conway, R. G. Barradas, and T. Zawidzki, J. Phys. Chem.62, 676 (1958).

    Google Scholar 

  15. B. E. Conway and J. M. Bockris (ed.), Modern Aspects of Electrochemistry, No. 7, London: Plenum. 1972.

    Google Scholar 

  16. W. J. Blaedel and D. E. Dinwiddie, Analyt. Chemistry46, 873 (1974).

    Google Scholar 

  17. S. N. K. Chaudhari and K. L. Cheng, Mikrochim. Acta [Wien]1979 II, 411.

    Google Scholar 

  18. G. Eisenman (ed.), Glass Electrodes for Hydrogen and Other Cations: Principle and Practice, New York: Dekker. 1967.

    Google Scholar 

  19. S. N. K. Chaudhari, F. C. Chang, K. L. Cheng, and V. Y. Young, to be published.

  20. Orion Research, Analytical Methods Guide, Oct., 1972.

  21. S. N. K. Chaudhari, K. L. Cheng, and V. Y. Young, to be published.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Missouri, Kansas City, Missouri, USA

    Sunetra N. Kar Chaudhari & K. L. Cheng

Authors
  1. Sunetra N. Kar Chaudhari
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. L. Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kar Chaudhari, S.N., Cheng, K.L. Radioactive tracer study of adsorption and exchange reaction of lead ion selective electrode membrane. Mikrochim Acta 74, 159–170 (1980). https://doi.org/10.1007/BF01196441

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01196441

Keywords

Search

Navigation