Abstract
The possibility of using diantipyrylmethane as an ionophore component of a lead-selective electrode membrane was assessed. Membrane composition (wt %) was optimized: polyvinyl chloride (31.89), dioctyl sebacate (63.81), diantipyrylmethane (2.50), and oleic acid (1.80). The proposed model of the electrode works in the concentration range of 1 × 10–5–0.1 M with a detection limit of 2 mg/L. A slope of the electrode function of the diantipyrylmethane-based electrode is 29.4 ± 0.5 mV/pPb. Concentration of Pb(II) ions in various samples was determined.
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Original Russian Text © S.D. Tataeva, V.S. Magomedova, K.E. Magomedov, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 11, pp. 1172–1176.
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Tataeva, S.D., Magomedova, V.S. & Magomedov, K.E. Determination of lead ions using an diantipyrylmethane-based electrode. J Anal Chem 71, 1115–1119 (2016). https://doi.org/10.1134/S1061934816110149
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DOI: https://doi.org/10.1134/S1061934816110149