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Stereoselective chlorination of phenylacetylene compounds in the systems K2S2O8-MCln-pyridine

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Abstract

It was shown that the main products of oxidative chlorination of acetylenes by the system K2S2O8-MCln in pyridine are transdichloroalkenes. It was established that the formation of chloro-derivatives from unsaturated hydrocarbons proceeds only in the presence of ions of metals of variable valence (Cu2+, Co2+, Fe3+). A possible reaction scheme is proposed.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Ul. Murmanskaya, GSP, 252660, Kiev-94, Ukraine

    R. B. Gutsulyak, V. N. Britsun & Yu. A. Serguchev

Authors
  1. R. B. Gutsulyak
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  2. V. N. Britsun
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  3. Yu. A. Serguchev
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 31, No. 4, pp. 243–246, July–August, 1995.

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Gutsulyak, R.B., Britsun, V.N. & Serguchev, Y.A. Stereoselective chlorination of phenylacetylene compounds in the systems K2S2O8-MCln-pyridine. Theor Exp Chem 31, 200–202 (1995). https://doi.org/10.1007/BF01195927

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  • DOI: https://doi.org/10.1007/BF01195927

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