Skip to main content
SpringerLink
Log in

Synthesis ofω,ω,ω-trichloroalkylamines andω, ω-dichloroalkenylamines

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the reaction of tetrachloroalkanes and trichlorcalkenes having the structures CCl3(CH2)nCl and CCl2 = CH(CH2)nCl with ammonia, the following amines have been prepared: CCl2(CH2)4NH2, CCl3(CH2)6NH2. CCl2 =CH(CH2)3NH2. CCl2 =CH(CH2)5. NH2CCl3 = CH(CH2)4NH2, and their benzoyl derivatives.

  2. 2.

    Hydrogenation of polychlorc nitriles of structure CCl3(CH2)4CN and CCl2 =CH(CH2)3CN by means of hydrogen under pressure vi presence pf Raney nickel has yielded amines of structure;CHCl2CH2);NH2 and CCl2 =CH(CH2)3NH2 and their benzoyl derivatives.

  3. 3.

    6,8,6-Trichlorchexylainine has been prepared by the action of hydrazoic acid on 7,7,7-trichloroheptanoic acid. Tie trichloroheptinoic acid was prepared from 1,1,1,5-terrachlorop;rttane by the malonic ester synthesis. The acid chloride and amide of 7,7,7-trichloroheptanoic acid have been prepared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. N. Nesmeyanov, R. Kh. Freidlina, and V. 1. Firstov, Bull.. Acad. Sci. USSR, Div. Chem., Sci., No. 5, 505 (1951).

  2. A. N. Nesmeyanov, R. Kh. Freidlina, and L. I. Zakharkin, Proc. Acad. Sci. USSR, 81, 199 (1951).

    Google Scholar 

  3. A. N. Nesrnayanov and L. I. Zakharkir., Bull. Acad. Sci. USSR. Div. Chem. Sci., No. 6, 938 (1953).

  4. S. Malkiel, J. Ph. Meser, J. Am. Chem. Soc., 64, 2515 (1942).

    Google Scholar 

  5. Brit. Pat. 652,768; C. A. 46, 1577 (1952).

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    A. N. Nesmeyanov, L. I. Zakharkin & R. Kh. Freidlina

Authors
  1. A. N. Nesmeyanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Zakharkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Kh. Freidlina
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nesmeyanov, A.N., Zakharkin, L.I. & Freidlina, R.K. Synthesis ofω,ω,ω-trichloroalkylamines andω, ω-dichloroalkenylamines. Russ Chem Bull 3, 27–32 (1954). https://doi.org/10.1007/BF01195421

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01195421

Keywords

Search

Navigation