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Crystal structure of dicyclohexylammonium 2-mercaptobenzoatotriphenylstannate

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Abstract

Dicyclohexylammonium 2-mercaptobenzoatotriphenylstannate crystallizes in the monoclinicP21/n space group (a=11.171(2),b=17.891(5),c=17.190(3)Å;β=105.08(2)°). The asymmetric unit consists of a [(cyclo-C6H11)2NH2]+ cation hydrogen bonded (N⋯O1=2.803(4) Å) to the stannate anion; the [(C6H5)3Sn]+ group is covalently linked to the sulfur end (Sn-S=2.427(1)Å) of the [SC6H4C(O2)O1]−2 moiety. The tin is five-coordinate in a distortedcis-trigonal bipyramidal environment in which the carboxyl O2 atom (Sn-O2=2.704(3)Å) and theipso-carbon of a phenyl ring occupy apical positions (O2-Sn-C1=168.7(1)°); the Sn-Caxial bond (Sn-C1=2.179(3)Å) is longer than the Sn-Cequatorial bonds (2.136(4), 2.139(3)Å). The stannate anion is linked to an adjacent cation (N′⋯O1=2.880(4)Å) to form a tightly held three-dimensional network structure.

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Authors and Affiliations

  1. Institute of Advanced Studies, University of Malaya, 59100, Kuala Lumpur, Malaysia

    Seik Weng Ng

  2. Department of Chemistry, University of Malaya, 59100, Kuala Lumpur, Malaysia

    V. G. Kumar Das

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  1. Seik Weng Ng
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  2. V. G. Kumar Das
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Weng Ng, S., Kumar Das, V.G. Crystal structure of dicyclohexylammonium 2-mercaptobenzoatotriphenylstannate. Journal of Crystallographic and Spectroscopic Research 23, 925–928 (1993). https://doi.org/10.1007/BF01185537

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  • DOI: https://doi.org/10.1007/BF01185537

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