Abstract
An analysis of the IR spectral patterns of a series ofM 2(CO)10−n (L) n complexes (whereM=Re, Mn; L=CNR, PR 3;R=Alkyl, Aryl;n=1−3), taking as far as possible example structures that have been determined by X-ray crystallography, has enabled a correlation to be established between the number and intensity ofv(CO) IR bands and the substitution geometry of the complex. Such a set of standard IR spectral patterns can be used as an easy means of verifying the substitution geometry of such complexes.
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Harris, G.W., Coville, N.J. Relating infra red spectral data to structure for a series of M2(CO)10−n(L)n complexes (M=Re, Mn; L=CNR, PR3; R=Alkyl, Aryl; n=1−4). Journal of Crystallographic and Spectroscopic Research 19, 451–464 (1989). https://doi.org/10.1007/BF01185382
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DOI: https://doi.org/10.1007/BF01185382