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Structural investigation on hexasubstituted benzene derivatives. Part 1. The structure of ortho-dinitrotetramethylbenzene

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Abstract

C10H12N2O4 (M r =224.2) crystallizes in the triclinic system, space groupP¯1 witha=8.327(3),b=8.734(3),c=8.453(3) Å;a=63.6(1),β=97.0(1), γ=100.4(1)°;V=541.0(6) Å3,Z=2,D c =1.38 g cm−3,μ(Cu-Kα)=8.7 cm−1, λ=1.5418 Å, F(000)=236. Deviation from theoretic geometry of the benzene ring and from planarity is observed in accordance with theσ-electron-withdrawing character of the NO2 groups and the high steric hindrance of the substituents.

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References

  • Akopyan, Z. A., Struchkov, Yu. T., and Dashevii, V. G. (1966)Zh. Strukt. Khim. 7, 408.

    Google Scholar 

  • Beletti, D., Ugozzoli, F., Cantoni, A., and Pasquinelli, G. (1979) Gestione on Line di Diffratto-metro a Cristallo Singolo Siemens AED con Sistema General Automation Jumbo 220, Centro di Studio per la Strutturistica Diffrattometrica del C.N.R., Parma, Int. Rep. 1-3/79.

    Google Scholar 

  • Cataliotti, R. S., Paliani, G., and Sorriso, S. (1986)J. Chem. Phys. 85, 5575.

    Google Scholar 

  • Domenicano, A., Vaciago, A., and Coulson, C. A. (1975)Acta Cryst. B31, 221.

    Google Scholar 

  • Gatilov, Yu. V., Bokii, N. G., and Struchkov, Yu. T. (1975)Zh. Strukt. Khim. 16, 702.

    Google Scholar 

  • Lehmann, M. S., and Larsen, F. K. (1974)Acta Cryst. A30, 580.

    Google Scholar 

  • Main, P., Woolfson, M. M., and Germain, G. (1972)Multan,A Computer Program for the Automatic Solution of Crystal Structures (University of York, England).

    Google Scholar 

  • Pauling, L. (1960) Nature of the Chemical Bond, (Cornell University Press).

  • Sheldrick, G. M. (1976)Shelx 76,Program for Crystal Structure Determination (University of Cambridge, England).

    Google Scholar 

  • Sorriso, S. (1982)Z. Phys. Chem. N. F. 131, 37.

    Google Scholar 

  • Sorriso, S., and Santini, S. (1982)Z. Phys. Chem. N. F. 129, 161.

    Google Scholar 

  • Tanaka, L., Iwasaki, F., and Aihara, A. (1974)Acta Cryst. B30, 1546.

    Google Scholar 

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Authors and Affiliations

  1. Istituto di Strutturistica Chimica, Università degli Studi di Parma Centra di Studio per la Strutturistica Diffrattometrica del C. N. R., Viale delle Scienze, I-43100, Parma, Italy

    Paolo Sgarabotto & Franco Ugozzoli

  2. Dipartimento di Chimica, Università di Perugia, I-06100, Perugia, Italy

    Salvatore Sorriso

Authors
  1. Paolo Sgarabotto
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  2. Franco Ugozzoli
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  3. Salvatore Sorriso
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Sgarabotto, P., Ugozzoli, F. & Sorriso, S. Structural investigation on hexasubstituted benzene derivatives. Part 1. The structure of ortho-dinitrotetramethylbenzene. Journal of Crystallographic and Spectroscopic Research 19, 905–910 (1989). https://doi.org/10.1007/BF01185356

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  • DOI: https://doi.org/10.1007/BF01185356

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