Abstract
The adsorption of alkylphenylpoly(oxyethylene)alcohol on E-glass fibres was characterized by X-ray photoelectron spectroscopy, by the Wilhelmy plate method and by streaming-potential measurements. In this study, the glass fibres were conditioned in solutions of different pH. The acid resistance of the E-glass fibres was studied by treating the material with H2SO4. During the acid treatment the surface composition, namely the Si/Al-ratio, was changed, presumably because the aluminium ions were leached out of the glass structure. The alkaline resistance was studied by treating the material with NaOH. The Si/Al-ratio was unaffected by these moderate alkaline solutions. The effect of the surface conditioning in solutions of different pH seemed to be greatest for the acidic solutions giving rise to an increased adsorption of the surfactant on the glass-fibre surface.
Similar content being viewed by others
References
K. L. Loewenstein, “The manufacturing technology of continuous glass fibres” (Elsevier Scientific, Amsterdam, 1973).
5000 Series ESCA System Manual, Technical Manual. Perkin-Elmer, Physical Electronics Division, Eden Prairie USA, 1988.
J. Schurz andG. Erk,Progr. Colloid, Polym. Sci. 71 (1985) 44–48.
H. M. Fagerholm, C. Lindsjö, J. B. Rosenholm andK. Rökman,Colloids Surfaces 69 (1992) 79–86.
D. J. Shaw, “Introduction to colloid and surface chemistry” (Butterworth, London, 1980) pp. 127–136.
S. K. Li, R. P. Smith andA. W. Neumann,J. Adhesion 17 (1984) 105–122.
L. S. Penn andB. Miller,J. Colloid Interface Sci. 77 (1980) 574–576.
B. Miller, L. S. Penn andS. Hedvat,Colloids Surfaces 6 (1983) 49–61.
B. E. Ramachandran, B. C. Pai andN. Balasubramanian,J. Amer. Ceram. Soc. 63 (1980) 1–3.
R. K. Iler, “The chemistry of silica, solubility, polymerisation, colloid and surface properties and biochemistry” (Wiley-Interscience and Wiley, New York, 1978).
J. Jednacak andV. Pravdic,J. Colloid Interface Sci. 49 (1974) 16–23.
G. D. Parfitt, “Adsorption from solution at the solid/liquid interface” (edited by C. H. Rochestes Academic Press, 1983) Ch. 3.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fagerholm, H.M., Lindsjö, C. & Rosenholm, J.B. Physical characterization of E-glass fibres treated with alkylphenylpoly(oxyethylene) alcohol — fibres conditioned in solutions of different pH. J Mater Sci 30, 2420–2424 (1995). https://doi.org/10.1007/BF01184595
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01184595