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Ab initio self-consistent theory of ionic diffusion in superionic conductors with an internal interface

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Abstract

The kinetic equation of the hopping diffusion in a one-dimensional chain with an internal interface between a superionic conductor and an intercalate, is presented in a new form, which explicitly takes into account the effect of Coulomb correlations. Numerical results are presented for material parameters corresponding to the system: ternary borate glass-indium selenide, which is often used in solid microbatteries.

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Author notes

  1. I. Nachev

    Present address: Institute of Electronics, Bulgarian Academy of Sciences, bul. Zarigradsko Shose 72, 1784, Sofia, Bulgaria

Authors and Affiliations

  1. Modelling of Superionic Devices, ul. “Zografski Manastir”, bl. 119, vh. “A”, ap. 39, 1309, Sofia, Bulgaria

    I. Nachev

  2. Laboratoire de Physique des Solides, Université Pierre et Marie Curie, (CNRS 154), 4, place Jussieu, T13-E2, 75252 Paris, France

    M. Balkanski

Authors
  1. I. Nachev
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  2. M. Balkanski
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Nachev, I., Balkanski, M. Ab initio self-consistent theory of ionic diffusion in superionic conductors with an internal interface. J Mater Sci 30, 2296–2298 (1995). https://doi.org/10.1007/BF01184576

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  • DOI: https://doi.org/10.1007/BF01184576

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