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Reactions of chloro(trimethylsiloxy)silanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The aminolysis of chloro(trimethylsiloxy)silanes proceeds with replacement of halogen by an amino group without elimination of the trimethylsiloxy group.

  2. 2.

    Double decomposition of sodium tristrimethylsiloxysiloxide with titanium tetrachloride leads to the formation of a compound of cruciform structure, namely tetrakis(tristrimothylsiloxysiloxy)titanium.

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Literature cited

  1. K. A. Andrianov, V. V. Severnyi and B. G. Zavin, Izv. AN SSSR. Otd. khim. n. 1456(1961).

  2. Brit. Pat. 627136, Chem. Abstrs. A.44, 4284 (1950).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    K. A. Andrianov & N. V. Delazari

Authors
  1. K. A. Andrianov
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  2. N. V. Delazari
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Andrianov, K.A., Delazari, N.V. Reactions of chloro(trimethylsiloxy)silanes. Russ Chem Bull 10, 2028–2031 (1961). https://doi.org/10.1007/BF01182947

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  • DOI: https://doi.org/10.1007/BF01182947

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