Summary
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1.
The following dicyclopentadienyl titanium derivatives containing acyl groups we're synthesized:
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2.
It was shown to be'possible to prepare monoalkoxy- and mono(aryloxy)-dicyclopentadienyltitanlum derivatives by the action of alcohols and phenols on (C5H5)2TiCl2 in presence of a tertiary amine.
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3.
By the action of C5H5Na on (CH3)3SiOTiCl3 we obtained (C5H5)2Ti · [OSi(CH3)3]Cl and C5H5Ti[OSi(CH3)3]3.
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4.
The refraction increment of the titanium-cyclopentadienyl ring group (Including the atomic refraction of titanium) was determined and found to be 35.28.
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Nesmeyanov, A.N., Nogina, O.V., Berlin, A.M. et al. Acyl and alkoxy derivatives of dicyclopentadienyltitanium and the refraction increment of the π-C5H5Ti group. Russ Chem Bull 10, 2008–2012 (1961). https://doi.org/10.1007/BF01182943
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DOI: https://doi.org/10.1007/BF01182943