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Structure oftrans-dichlorotetrakis(thiazole)Rh(III) perchlorate·acetonitrile solvate

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Abstract

The title compound [RhCl2(SNC3H3)4] [ClO4]·CH3CN is monoclinic, witha=23.791(4),b=7.253(2),c=14.498(2)Å,β=105.24(1)°,V=2414(1)Å3,Z=4,D x =1.802,μ(MoKα)=13.95 cm−1,F(000)=1304,T=298K in space group Cc. The structure was solved by heavy atom and Fourier methods and refined toR=0.047 for 4742 unique observed reflections. The cation is nearly octahedral, with thecis andtrans angles about the Rh in the range from 89.2(2) to 90.8(2)° and 179.4(2) to 180.0(2)°, respectively. Average Rh-Cl and Rh-N bond lengths are 2.337(2) and 2.036(6)Å. One of the thiazole ligands showed disorder between the S and one of the C atoms in the ring.

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Authors and Affiliations

  1. Department of Chemistry, University of Puerto Rico, Río Piedras, 00931, Puerto Rico

    Yong Ji Li & Rong Ma

  2. School of Science, Southwest Texas State University, 601 University Drive, 78666, San Marcos, Texas

    Mariel M. Muir & James A. Muir

Authors
  1. Yong Ji Li
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  2. Rong Ma
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  3. Mariel M. Muir
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  4. James A. Muir
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Li, Y.J., Ma, R., Muir, M.M. et al. Structure oftrans-dichlorotetrakis(thiazole)Rh(III) perchlorate·acetonitrile solvate. Journal of Crystallographic and Spectroscopic Research 23, 493–496 (1993). https://doi.org/10.1007/BF01182525

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  • DOI: https://doi.org/10.1007/BF01182525

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