Abstract
The crystal structures of three CH3Hg+ complexes with 1,3-thiazolidine-2-thione (HT) are reported. The cationic [(CH3Hg)HT]NO3 complex is monoclinic, space group P21/c,a=7.158(14),b=10.156(7),c=13.472(12) Å,β=108.21(4)°,Z=4. The structure was refined toR=0.045. The [(CH3Hg)HT]+ cation contains a CH3Hg+ group bonded to the exocyclic S atom of the ligand retaining its N-H proton. This proton is lost and the CH3Hg+ group remains bonded to sulfur in the neutral [(CH3Hg)T] compound (hexagonal, P63,a=13.502(8),c=6.984(7) Å,Z=6,R=0.027). The [(CH3Hg)2T]NO3 compound (monoclinic, C2/c,a=25.200(10),b=7.029(6),c=17.946(8),β=128.99(3)°,Z=8,R=0.047) contains complex cations in which the CH3Hg+ groups are bonded to N and the exocyclic S atom. This series of compounds shows that the exocyclic S atom is always the first target for the CH3Hg+ group, which is also found to bind to nitrogen in the 2:1 compound. No coordination is observed with the endocyclic S site, which does not even participate in intermolecular H-bonding or Hg⋯S contacts in the solids.
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Norris, A.R., Palmer, A. & Beauchamp, A.L. Crystal structures of three methylmercury(II) complexes with thiazolidine-2-thione. Journal of Crystallographic and Spectroscopic Research 20, 23–30 (1990). https://doi.org/10.1007/BF01181671
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DOI: https://doi.org/10.1007/BF01181671