Skip to main content
SpringerLink
Log in

(Aroxymethyl)triphenyltin compounds: Crystal and molecular structure of triphenyl(p-toloxymethyl)tin

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

Compounds, Ph3SnCH2OAr, are available from Ph3SnCH2I and NaOAr in EtOH. The crystal and molecular structure of Ph3SnCH2OC6H4Me-p (II) has been determined by X-ray crystallography. The molecule in the crystal contains a slightly distorted tetrahedral tin atom [C-Sn-C valency angles varying from 106.9(5) to 114.1(6)°] with an intramolecular Sn---O distance of 2.900(11) Å. NMR spectral data for (II) and for Ph3SnCH2OC6H3Br2-2,4 are reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Berges, J., and Perrin, H. (1981)J. Chim. Phys. Phys.-Chem. Biol. 78, 573.

    Google Scholar 

  • Bock, H., Wagner, G., and Kroner, J. (1972)Chem. Ber. 105, 3850.

    Google Scholar 

  • Cox, P. J., Doidge-Harrison, S. M. S. V., Nowell, I. W., Howie, R. A., Randall, A. P., and Wardell, J. L. (1990a)Inorg. Chim. Acta 172, 225.

    Google Scholar 

  • Cox, P. J., Doidge-Harrison, S. M. S. V., Nowell, I. W., Howie, R. A., Randall, A. P., and Wardell, J. L. (1990b)Inorg. Chim. Acta 176, 155.

    Google Scholar 

  • Dewer, P. S., Ernstbrunner, L., Gilmore, J. R., Godfrey, M., and Mellor, J. M. (1974)Tetrahedron 30, 2455.

    Google Scholar 

  • Dodziuk, H., von Voithenberg, H., and Allinger, N. L. (1982)Tetrahedron 38, 2811.

    Google Scholar 

  • Gerhards, J., Ha, T-K., and Perlia, X. (1982)Helv. Chim. Acta 65, 105.

    Google Scholar 

  • Goldberg, I. (1980) InThe Chemistry of Ethers, Crown Ethers, Hydroxyl Groups and their Sulphur Analogues, Supplement E., Patai, S. (ed.) (Wiley, Chichester), Chap. 4.

    Google Scholar 

  • Kennedy, J. D., McFarlane, W., Pyne, G. S., Clarke, P. L., and Wardell, J. L. (1975)J. Chem. Soc. Perkin Trans. 2, 1234.

    Google Scholar 

  • Lister, D. G., and Owen, N. L. (1973)Trans. Faraday Soc. II, 304.

    Google Scholar 

  • Mallinson, P. R., and Muir, K. W. (1985)J. Appl. Crystallogr. 18, 51.

    Google Scholar 

  • Martinetti, A., and Mathey, F. (1988)Angew. Chem. Int. Ed. Engl. 27, 1381.

    Google Scholar 

  • McDonough, C. R., Taylor, O. J., and Wardell, J. L. (1989)Appl. Organomet. Chem. 3, 417.

    Google Scholar 

  • Olah, G. A., and Forsyth, D. A. (1975)J. Am. Chem. Soc. 97, 3137.

    Google Scholar 

  • Pereye, M., Quintard, J.-P., and Rahm, A. (1987)Tin in Organic Synthesis (Butterworths, London), p. 161.

    Google Scholar 

  • Seip, H. M., and Seip, R. (1973)Acta Chem. Scand. 27, 4024.

    Google Scholar 

  • Seyferth, D., and Andrews, S. B. (1971)J. Organomet. Chem. 77, 311.

    Google Scholar 

  • Sheldrick, G. M. (1976)Shelx 76. Program for Crystal Structure Determination (University of Cambridge, England).

    Google Scholar 

  • Taylor, R. D., and Wardell, J. L. (1974)J. Organomet. Chem. 77, 311.

    Google Scholar 

  • Taylor, R. D., and Wardell, J. L. (1976)J. Chem. Soc. Dalton Trans 1345.

  • Wardell, J. L. (1989) InChemistry of Tin, Harrison, P. G. (ed.) (Blackie, Glasgow), p. 343.

    Google Scholar 

  • Wigzell, J. McM., Taylor, R. D., and Wardell, J. L. (1982)J. Organomet. Chem. 235, 29.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Pharmacy, The Robert Gordon Institute of Technology, Schoolhill, AB9 1FR, Aberdeen, Scotland

    Philip J. Cox

  2. School of Applied Sciences, The Robert Gordon Institute of Technology, St. Andrew St., AB1 1HG, Aberdeen, Scotland

    Solange M. S. V. Doidge-Harrison

  3. Chemistry Department, University of Aberdeen, AB9 2UE, Meston Walk, Old Aberdeen, Scotland

    R. Alan Howie & James L. Wardell

Authors
  1. Philip J. Cox
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Solange M. S. V. Doidge-Harrison
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. Alan Howie
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. James L. Wardell
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cox, P.J., Doidge-Harrison, S.M.S.V., Howie, R.A. et al. (Aroxymethyl)triphenyltin compounds: Crystal and molecular structure of triphenyl(p-toloxymethyl)tin. Journal of Crystallographic and Spectroscopic Research 21, 735–739 (1991). https://doi.org/10.1007/BF01179921

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179921

Keywords

Search

Navigation