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Investigation of peroxyhydrates and hydrates of rubidium and cesium carbonates

Communication 3. Physicochemical study of the ternary system Cs2CO3-H2O2-H2O

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An investigation of the solubility in the system Cs2CO3 — H2O2 — H2O at − 10, − 21, and − 40° demonstrated the existence of two solid phases: ice and cesium carbonate peroxyhydrate, with the composition Cs2CO3 · 3H2O2.

  2. 2.

    The existence of cesium carbonate peroxyhydrates with a higher H2O2 content was not established.

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Literature cited

  1. T. A. Dubrynina and B. S. Dzyatkevich, Izv. AN SSSR, Ser. Khim.,1964, 790.

  2. B. S. Dzyatkevich and T. A. Dubrynina, Chemistry of Peroxide Compounds [in Russian], Izd. AN SSSR, Moscow (1963), p. 112.

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  3. S. Z. Makarov and T. A. Dubrynina, Izv. AN SSSR, Otd. Khim. N.,1955, 411.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    T. A. Dobrynina & B. S. Dzyatkevich

Authors
  1. T. A. Dobrynina
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  2. B. S. Dzyatkevich
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1881–1884, November, 1966.

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Dobrynina, T.A., Dzyatkevich, B.S. Investigation of peroxyhydrates and hydrates of rubidium and cesium carbonates. Russ Chem Bull 15, 1821–1823 (1966). https://doi.org/10.1007/BF01179686

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  • DOI: https://doi.org/10.1007/BF01179686

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