Summary
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1.
With ethanethiol ψ-, α-, and β-ionones form diethyl mercaptoles. Benzylideneacetone reacts with ethanethiol not only at the carbonyl group, but also at the double bond, with formation of 1,3,3-trisethylthio-1-phenylbutane.
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2.
When heated in presence of a catalytic amount of zinc chloride, the diethyl mercaptoles of ψ-, α-, and β -ionones are converted with elimination of a molecule of ethanethiol into unsaturated Sulfides of the type
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Communication 15 was published in Zh. obshchei khimii32,446 (1962).
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Mikhailov, B.M., Ter-Sarkisyan, G.S. & Bystrova, A.A. Polyenic compounds. Russ Chem Bull 13, 38–41 (1964). https://doi.org/10.1007/BF01179563
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DOI: https://doi.org/10.1007/BF01179563