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Reactivities of certain aromatic and heteroaromatic compounds in the lower excited triplet state

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The INDO approximation of the SCF MO LCAO method has been used to carry out calculations on the lower triplet state of aromatic molecules with type I substiuents (fluorobenzene, phenol, and aniline), five-membered heteroaromatic compounds (furan and pyrrole), and their cation and anionσ complexes.

  2. 2.

    The experimental data on the photochemical aromatic electrophilic and nucleophilic substitution reactions have been analyzed. It is pointed out that it is possible that these reactions proceed through a triplet σ complex.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. A. Abronin, L. I. Belen'kli & G. M. Zhidomirov

Authors
  1. I. A. Abronin
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  2. L. I. Belen'kli
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  3. G. M. Zhidomirov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 588–594, March, 1977.

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Abronin, I.A., Belen'kli, L.I. & Zhidomirov, G.M. Reactivities of certain aromatic and heteroaromatic compounds in the lower excited triplet state. Russ Chem Bull 26, 528–532 (1977). https://doi.org/10.1007/BF01179460

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  • DOI: https://doi.org/10.1007/BF01179460

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