Summary
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1.
It has been established that, when silicon tetrafluoride reacts with e two-fold excess of phenyl- or ptolyl-magnesium bromide under the conditions of the Grignard synthesis, the corresponding tetraarylsilane is obtained in good yield.
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2.
Fluorotri-p-tolylsilane has been synthesized for the first time, and some of its properties have been determined.
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Chugunov, V.S. Grignard synthesis of tetra phenylsilane, tetra-p-tolysilane and fluorotri-p-tolylsilane. Russ Chem Bull 2, 761–762 (1953). https://doi.org/10.1007/BF01178854
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DOI: https://doi.org/10.1007/BF01178854