Summary
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1.
The vinyl ether of 3-(diethylmethylsilyl)-1-propanol was synthesized by a modification of the Favorsky-Shostakovsky method.
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2.
A study was made of the reactions of the vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol with water, organic and organosilicon alcohols, and organic acids.
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3.
3-(Diethylmethylsilyl)-1-propanol, its vinyl ether, four organosilicon acetals, and three acylals were prepared for the first time.
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4.
It was shown that, under similar conditions, the vinyl ether of 3-(diethylmethylsilyl)-1-propanol and organosilicon acetals and acylals are hydrolyzed with greater difficulty than their organic analogs.
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Literature cited
M. F. Shostakovsky, Vinyl Ethers, Acad. Sci. USSR Press, Moscow, 1952.
M. F. Shostakovsky and I. A. Shikhiev, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1954, 745.
I. A. Shikhiev and N. V. Komarov, Proc. Acad. Sci. USSR 108, No. 2, 279 (1956).
M. F. Shostakovsky, I. A. Shikhiev, M. V. Vlasov, and V. I. Belaev, Proc. Acad. Sci. Azerbaidzhan SSR,No. 7, 473 (1954).
I. A. Shikhiev, Proc. Acad. Sci. Azerbaidzhan SSR No. 4, 243 (1955).
M. F. Shostakovsky and E. N. Prilezhaeva, J. Gen. Chem. 17, 1129 (1946).
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Shostakovsky, M.F., Shikhiev, I.A. & Komarov, N.V. Synthesis and reactions of oxygen-containing organosilicon compounds Communication 3. Synthesis and some reactions of vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol. Russ Chem Bull 5, 1535–1541 (1956). https://doi.org/10.1007/BF01177536
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DOI: https://doi.org/10.1007/BF01177536