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Effect of the method of preparation and the presence of a carrier on the catalytic activity of chromic oxide in dehydrogenation and dehydration reactions

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Activation energies were determined for the dehydrogenation of methylcyclohexane, isopropyl alcohol, and formic acid and the dehydration of isopropyl alcohol and formic acid over chromic oxide prepared in different ways. From these date the energies of the bonds formed by hydrogen, carbon, and oxygen with the chromic oxide surface were found.

  2. 2.

    The effect of molecular structure and the method of preparing the catalyst were investigated for these reactions.

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Literature Cited

  1. A. A. Balandin, J. Gen. Chem. 16, 793 (1946).

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  2. A. A. Balandin and A. A. Tolstopyatova, Proc. Acad. Sci. USSR 94, 49 (1954).

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  3. T. Cottrell, Strength of the Chemical Bond Foreign Lit. Press, Moscow, 1956).

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Authors and Affiliations

  1. S. Ordzbonikidze Moscow Aviation and N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    A. A. Tolstopyatova, K. A. Dulitskaya & A. A. Balandin

Authors
  1. A. A. Tolstopyatova
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  2. K. A. Dulitskaya
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  3. A. A. Balandin
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Tolstopyatova, A.A., Dulitskaya, K.A. & Balandin, A.A. Effect of the method of preparation and the presence of a carrier on the catalytic activity of chromic oxide in dehydrogenation and dehydration reactions. Russ Chem Bull 5, 1285–1294 (1956). https://doi.org/10.1007/BF01173788

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  • DOI: https://doi.org/10.1007/BF01173788

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