Skip to main content
Log in

Stability of the silicon-carbon bond in ar-chlorinated trichlorophenyl- and dichloroethylphenyl-silanes

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The hydrolysis of trichloro(chlorophenyl)silanes in acid and alkaline media was investigated, and it was shown that no elimination of chloro-, dichloro-, trichloro-, tetrachloro-, or pentachloro-phenyl group occurs.

  2. 2.

    The hydrolysis of dichloro(chlorophenyl)ethylsilanes in acid and alkaline media was investigated, and it was shown that no elimination of the ethyl group or of the mono-, di-, tri-, or tetra -chlorophenyl group occurs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. R. A. Benkeser, and H. R. Krysiak, J. Am. Chem. Soc. 75, 4528 (1953).

    Google Scholar 

  2. I. C. Eaborn, J. Chem. Soc. Ost. 3148 (1953).

  3. B. H. Meen and H. Gilman, J. Org. Chem. 20, No. 1, 73 (1955).

    Google Scholar 

  4. R. H. Krieble and I. R. Elliot, J. Am. Chem. Soc. 67, 1810 (1945).

    Google Scholar 

  5. R. H. Krieble and I. R. Elliot, J. Am. Chem. Soc. 68, 2291 (1946).

    Google Scholar 

  6. F. Whitmore and L. Sommer, J. Am. Chem. Soc. 68, 485 (1946).

    Google Scholar 

  7. E. Larsson and L. Knopp, Acta. chem. scand. I, 268 (1947).

    Google Scholar 

  8. H. Gilman, A. G. Brook and L. S. Miller, J. Am. Chem. Soc. 75, 4531 (1953).

    Google Scholar 

  9. H. Gilman and L. S. Miller, J. Am. Chem. Soc. 73, 968 (1951).

    Google Scholar 

  10. A. Ya. Yakubovich and G. V. Motsarev, J. Gen. Chem. 26, No. 2, 568 (1956).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Andrianov, K.A., Odinets, V.A. Stability of the silicon-carbon bond in ar-chlorinated trichlorophenyl- and dichloroethylphenyl-silanes. Russ Chem Bull 6, 988–993 (1957). https://doi.org/10.1007/BF01173595

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01173595

Keywords

Navigation