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  1. 1

    1. Methods proposed by Harrel, Clerc, and Zhuk for the calculation of protective potentials were examined. It was shown that these methods are useless for the calculation of protective potentials.

  2. 2.

    A new method for calculating protective potentials is described. It is based on.an exponential relationship between the rate of the anodic process of dissolution of metal and the potential.

  3. 3.

    The proposed method of calculating protective potentials of metals was verified for copper, zinc, cadmium, magnesium, lead, iron, and cast iron in 1.5% sodium chloride solution and for iron in artificial lake water. Close agreement between calculated and experimentally determined protective potentials was found.

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Literature cited

  1. D. Harrel, M. Clerc, Petrol. Eng. 11, No. 1, 38 (1939).

    Google Scholar 

  2. I. N. Frantsevich and T. F. Frantsevich-Zabludovskaya, J. Appl. Chem. 22, No. 8 (1949).

    Google Scholar 

  3. N. P. Zhuk, J. Phys. Chem. 28, No. 10, 1869 (1954).

    Google Scholar 

  4. R. B. Mears, R. R. Brown, Trans. Electrochem. Soc. 74, 519 (1938).

    Google Scholar 

  5. Ya. M. Kolotyrkin and A. N. Frumkin, J. Phys. Chem. 15, 347 (1941).

    Google Scholar 

  6. L. N. Yagupolskaya, Protective Potentials of Certain Metals under Conditions of Cathodic Protection, Thesis, Kiev, 1952.

  7. N. D. Tomashov, Proc. Acad. Sci. USSR 24, No. 2, 151 (1939).

    Google Scholar 

  8. G. R. Kehn, E. J. Wilhelm, Corrosion, No. 5, 156 (1951).

  9. Ya. M. Kolotyrkin and A. N. Frumkin, Proc. Acad. Sci. USSR 33, No. 7–8,451 (1941).

    Google Scholar 

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Gerasimov, V.V. Protective potentials of metals. Russ Chem Bull 6, 279–284 (1957). https://doi.org/10.1007/BF01173330

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  • DOI: https://doi.org/10.1007/BF01173330

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