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The reactions of dienic hydrocarbons with nitroso compounds. Addition of 1,3-butadiene to nitrosobenzene. Communication 2

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It has been found that when 3,6-dihydro-2-phenyl-1,2,2H-oxazine is reduced by means of zinc dust and acetic acid under severe conditions, 1-phenyl-3-pyrroline is formed. acetic acid under severe conditions, 1-phenyl-3-pyrroline is formed.

  2. 2.

    It has been found that when 3,6-dihydro-2-phenyl-1,2,2H-oxazine is reduced by means of sodium and alcohol, N-2-butenylaniline is formed.

  3. 3.

    It has been shown that when 3,6-dihydro-2-phenyl-1,2,2H-oxazine is reduced to give 1-phenyl-3-pyrroline, 4-phenylamino-2-buten-1-ol is formed as an intermediate product.

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Authors and Affiliations

  1. Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    Yu. A. Arbuzov

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  1. Yu. A. Arbuzov
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Arbuzov, Y.A. The reactions of dienic hydrocarbons with nitroso compounds. Addition of 1,3-butadiene to nitrosobenzene. Communication 2. Russ Chem Bull 1, 523–529 (1952). https://doi.org/10.1007/BF01172008

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  • DOI: https://doi.org/10.1007/BF01172008

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