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Reaction of 3,3,3-Tribromo- and 1,3,3,3-Tetrabromo-1-nitroprop-1-enes with Aliphatic Dienes

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Abstract

3,3,3-Tribromo- and 1,3,3,3-tetrabromo-1-nitroprop-1-enes reacted with 2-methyl- and 2,3-dimethylbuta-1,3-dienes to give cyclohexene, cyclohexane, and hepta-1,5-diene derivatives containing nitro and tribromomethyl groups. The products were characterized by IR and 1H and13C NMR spectra and X-ray diffraction data.

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ACKNOWLEDGMENTS

The NMR and IR spectral data were obtained at the Joint Spectral and Analytical Center (Herzen State Pedagogical University of Russia). The authors thank Joint Chemical Research Center (Siberian Branch, Russian Academy of Sciences) for performing spectral and analytical measurements.

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Authors and Affiliations

  1. Herzen State Pedagogical University of Russia, 191186, St. Petersburg, Russia

    N. A. Anisimova & E. K. Slobodchikova

  2. St. Petersburg State University of Industrial Technologies and Design, 191186, St. Petersburg, Russia

    N. A. Anisimova

  3. Altai State Agricultural University, 656049, Barnaul, Russia

    M. E. Ivanova

  4. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    T. V. Rybalova

  5. Novosibirsk State University, 630090, Novosibirsk, Russia

    T. V. Rybalova

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  1. N. A. Anisimova
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  2. E. K. Slobodchikova
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  3. M. E. Ivanova
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  4. T. V. Rybalova
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Correspondence to N. A. Anisimova.

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Anisimova, N.A., Slobodchikova, E.K., Ivanova, M.E. et al. Reaction of 3,3,3-Tribromo- and 1,3,3,3-Tetrabromo-1-nitroprop-1-enes with Aliphatic Dienes. Russ J Gen Chem 90, 1388–1397 (2020). https://doi.org/10.1134/S1070363220080022

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