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Synthesis and properties of derivatives ofsym-triazines 14. Cyanoethylation of 4,6-disubstituted 2-amino-sym-triazines

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Abstract

The cyanoethylation of 4,6-disubstituted 2-amino-sym-triazines containing alkyl trichloromethyl, and pyridyl groups was studied, and the corresponding dicyanoethyl derivatives were synthesized. It was shown that the yield of the latter and the duration of the reaction depend on the nature of the substituents in the ring of the initial amino-sym-triazines. A method of obtaining 2-(2-cyanoethyl)amino-sym-triazines is proposed based on the decyanoethylation and disproportionation of the dicyanoethyl derivatives as well as the trans-cyanoethylation.

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Authors
  1. V. I. Kelarev
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  2. V. N. Kosbelev
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  3. R. A. Karakhanov
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Additional information

I. M. Gubkin State Petroleum and Gas Academy, Moscow 117917. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 111–129, January, 1995. Original article submitted November 2, 1994.

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Kelarev, V.I., Kosbelev, V.N. & Karakhanov, R.A. Synthesis and properties of derivatives ofsym-triazines 14. Cyanoethylation of 4,6-disubstituted 2-amino-sym-triazines. Chem Heterocycl Compd 31, 99–106 (1995). https://doi.org/10.1007/BF01171301

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