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Catalytic reactions at the surface of solid calcium and potassium amides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

It was shown that isomerization of alkenes with displacement of the double bond and hydrogen exchange in ] hydrocarbons both belong to the class of acid-base reactions; they are catalyzed by amide ions in ammoniacal solutions and by solid amides under heterogeneous conditions.

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Literature cited

  1. A. I. Shatenshtein, Prog. Chem. 24, 377 (1955).

    Google Scholar 

  2. A. I. Shatenshtein, L. N. Vasil'eva and N. M. Dykhno, Proc. Acad. Sci. USSR 85, 381 (1952); J. Phys. Chem. 28, 196 (1954).

    Google Scholar 

  3. A. L. Shatenshtein and E. A. Izrailevich, Proc. Acad. Sci. USSR 108, 294 (l956).

  4. I. V. Gostunskaia and B. A. Kazanskii, J. Gen. Chem. 25, 1995 (1955).

    Google Scholar 

  5. I. V. Gostunskaia, N. I. Tiun'kina, and B. A. Kazanskii, Proc. Acad. Sci. USSR 108, 473 (1956).

    Google Scholar 

  6. I. I. Ioffe and S. Z. Roginskii, J. Phys. Chem. 31, 612 (1957).

    Google Scholar 

  7. A. I. Shatenshtein, J. Phys. Chem. 15, 246 (1941).

    Google Scholar 

  8. A. I. Shatenshtein and Ia. M. Varshavskii, J. Anal. Chem. 11, 746 (1956).

    Google Scholar 

  9. P. V. Paterson and F. W. Bergstrom, Ind. Eng. Chem. 6, 136 (1934).

    Google Scholar 

  10. C. A. Kraus and E. J. Cuy, J. Am. Chem. Soc. 45, 712 (1923).

    Google Scholar 

  11. H. A. Benesi, J. Am. Chem. Soc. 78, 5490 (1956).

    Google Scholar 

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Shatenshtein, A.I., Dubinskii, I.G., Iakovleva, E.A. et al. Catalytic reactions at the surface of solid calcium and potassium amides. Russ Chem Bull 7, 98–100 (1958). https://doi.org/10.1007/BF01170871

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  • DOI: https://doi.org/10.1007/BF01170871

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