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Oxidation-reduction systems for the initiation of free-radical processes Communication 8. Mechanism of the action of a system containing ethylenediamine and a hydroperoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the kinetics of reaction between ethylenediamine and cumene hydroperoxide in aqueous and aqueous-hydrocarbon media in presence of various amounts of iron salts. It was shown that there is no direct relation between the kinetics of the decomposition of the hydroperoxide and the kinetics of polymerization. It was shown that the initiation of polymerization is not directly related to the oxidation-reduction reactions and that polymerization continuesafter the complete decomposition of the hydroperoxide.

  2. 2.

    The composition of the decomposition products of the hydroperoxide was studied. The mechanism of the action of the system was examined in the light of the results obtained.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds of the Academy of Sciences of the USSR, USSR

    G. P. Belonovskaia, B. A. Dolgoplosk, Zh. D. Vasiutina & M. N. Kulakova

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  1. G. P. Belonovskaia
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  2. B. A. Dolgoplosk
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  3. Zh. D. Vasiutina
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  4. M. N. Kulakova
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Belonovskaia, G.P., Dolgoplosk, B.A., Vasiutina, Z.D. et al. Oxidation-reduction systems for the initiation of free-radical processes Communication 8. Mechanism of the action of a system containing ethylenediamine and a hydroperoxide. Russ Chem Bull 7, 21–31 (1958). https://doi.org/10.1007/BF01170856

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  • DOI: https://doi.org/10.1007/BF01170856

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