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Synthesis and reactions of oxygen-containing organosilicon compounds communication 4. Synthesis of the methyl; ethyl, propyl, and isopropyl dimethylphenylsilyl acétals of acetaldehyde

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The investigation established the effect of the structure and composition of the alkyl radical of an alkyl vinyl ether on the reactivity of the ether in the reaction of silyl acetal formation.

  2. 2.

    The following compounds were synthesized and characterized for the first time: a) methyl, ethyl, propyl, and isopropyl dimethylphenylsilyl acetals of acetaldehyde; b) 1,1,3,3-tetramethyl-1,3-diphenyldisilazane.

  3. 3.

    Chlorodimethylphenylsilane was prepared by a new method.

  4. 4.

    A new method was proposed for the determination of halogens in mixtures of chloro- and bromo-silanes.

  5. 5.

    The method of hydrolyzing acetals was improved.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    M. F. Shostakovsky & Kh. I. Kondratyev

Authors
  1. M. F. Shostakovsky
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  2. Kh. I. Kondratyev
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Shostakovsky, M.F., Kondratyev, K.I. Synthesis and reactions of oxygen-containing organosilicon compounds communication 4. Synthesis of the methyl; ethyl, propyl, and isopropyl dimethylphenylsilyl acétals of acetaldehyde. Russ Chem Bull 5, 829–834 (1956). https://doi.org/10.1007/BF01169987

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  • DOI: https://doi.org/10.1007/BF01169987

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