Summary
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1.
It was shown that reaction between diethyl arsenochloridite and triethyl phosphite does not result in the formation of the tetraethyl ester of (dihydroxyarsino)phosphonic acid, which contains an As-P bond. The products isolated were triethyl phosphate and triethyl arsenite.
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2.
It was shown that in the reactions of triethyl antimonite with arseno-chloridous and -dichloridous esters and with phenylarsonous dichloride, simple exchange between alkoxy groups and chlorine occurs with formation of arsenious and phenylarsonous esters and the corresponding antimono-chloridous and -dichloridous esters.
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Literature cited
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Kamai, G., Chadaeva, N.A. & Arbuzov, A.E. Reactions of phenylarsonous dichloride and of arsenochloridous and -dichloridous esters with triethyl phosphite and triethyl antimonite. Russ Chem Bull 6, 599–602 (1957). https://doi.org/10.1007/BF01169276
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DOI: https://doi.org/10.1007/BF01169276