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Synthesis of some alkenyl- and alkyl-silanes and their derivatives

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It has been shown for the first time that reduction by means of lithium hydride can be successfully extended to alkyihalosilanes and other classes of organosilicon compounds (alkenylhalosilanes, halo(haloalkyl)silanes, alkylethoxy-silanes), and in the last case reduction proceeds selectively, without affecting the halogen of the haloalkyl group.

  2. 2.

    It has been shown that diallylsilane undergoes thiocyanation in almost theoretical yield, and that allylsilane combines with HCl in accordance with Markovnikov's rule.

  3. 3.

    The results provide data that characterize the dependence -of the freezing points of some silanes on their structure. It has been shown also that the value of the refraction fof the Si-C bond is determined by the radical containing the carbon attached to silicon, In particular, for allyl attached to silicon this value should be taken as 2.68 ml/mole.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of the USSR Academy of Sciences, USSR

    V. A. Ponomarenko & V. F. Mironov

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  1. V. A. Ponomarenko
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  2. V. F. Mironov
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Ponomarenko, V.A., Mironov, V.F. Synthesis of some alkenyl- and alkyl-silanes and their derivatives. Russ Chem Bull 3, 423–427 (1954). https://doi.org/10.1007/BF01167820

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  • DOI: https://doi.org/10.1007/BF01167820

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