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Die Synthese von 2-Amino-5-fluorthiophenol und seine Umwandlung in Phenothiazine und deren Sulfone

Synthesis of 2-amino-5-fluorobenzenethiol and its conversion into phenothiazines and their sulphones

  • Organische Chemie und Biochemie
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Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Attempts have been made to synthesise 2-amino-5-fluorobenzenethiol through hydrolytic cleavage of 2-amino-6-fluorobenzothiazole. It has been converted into substituted 1-nitro phenothiazines by condensation with reactive halogenonitrobenzenes and the oxidation behaviour of phenothiazines to phenothiazine sulphones has been studied in detail.

Zusammenfassung

Es wurde versucht, 2-Amino-5-fluorthiophenol durch hydrolytische Spaltung von 2-Amino-6-fluorbenzothiatol darzustellen. Kondensation mit reaktiven Halogennitrobenzolen gab 1-Nitro-phenothiazine, deren Oxidation zu Phenothiazinsulfonen detailliert untersucht wurde.

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Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, Jaipur, Indien

    R. L. Mital & Prakash Chand Taunk

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  1. R. L. Mital
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  2. Prakash Chand Taunk
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Mital, R.L., Taunk, P.C. Die Synthese von 2-Amino-5-fluorthiophenol und seine Umwandlung in Phenothiazine und deren Sulfone. Monatshefte für Chemie 102, 760–762 (1971). https://doi.org/10.1007/BF01167255

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  • DOI: https://doi.org/10.1007/BF01167255

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