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Oxidative addition of 2,2′-dithiosalicylic acid to the cluster [Os3(CO)10)(CH3CN)2]

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Abstract

The reaction of 2,2'-dithiosalicylic acid with two equivalents of [Os3(CO)10 (CH3CN)] in THF at −78°C yields yellow crystals of [{Os3(CO)10(μ-H)}2 (O2CC6H4S)2] 1 in moderate yield. Hydrogenetaion of 1 in refluxing CHCl3 affords [Os3(CO)1(μ-H)(O2CC6H5)] 2 in good yield. Structures of 1 and 2 have been established by single crystal X-ray structure analysis.

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Authors and Affiliations

  1. Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong

    Siu-Ming Lee & Wing-Tak Wong

  2. Centre for Materials Science, The University of Hong Kong, Pokfulam Road, Hong Kong

    Wing-Tak Wong

Authors
  1. Siu-Ming Lee
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  2. Wing-Tak Wong
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Lee, SM., Wong, WT. Oxidative addition of 2,2′-dithiosalicylic acid to the cluster [Os3(CO)10)(CH3CN)2]. J Clust Sci 7, 37–47 (1996). https://doi.org/10.1007/BF01166175

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  • DOI: https://doi.org/10.1007/BF01166175

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