Abstract
The method of EPR under conditions of the electrochemical production of free radicals of N-unsubstituted derivatives of 1,4-dihydro-3,5-dinitropyridine was utilized to confirm the formation of dianion-radicals, and their structure was established. The methods of polarography and cyclic voltamperometry were utilized to show the possible formation of anion-radicals of the N-substituted derivative of 1,4-dihydro-3,5-dinitropyridine which, however, could not be registered by the method of EPR due probably to the π-dimeric diamagnetic state of these species.
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Latvian Institute of Organic Synthesis, Riga LV-1006. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 936–943, July, 1996. Original article submitted October 2, 1995.
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Stradyn', Y., Baumane, L., Gavars, R. et al. Free anion-radicals in the electrochemical reduction of derivatives of 1,4-dihydro-3,5-dinitropyridine. Chem Heterocycl Compd 32, 800–806 (1996). https://doi.org/10.1007/BF01165724
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DOI: https://doi.org/10.1007/BF01165724