Skip to main content
SpringerLink
Log in

Highly polarized enamines. 2. Synthesis and investigation of the further amination of derivatives of α,α-DIAMINO-β-cyano-β-nitroethylene

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Highly polarized enediamines of the a, α-diamino-β-cyano-β-nitroethylene type have been obtained by the hydrolysis of 4-chloro-5-nitropyrimidines. Several chemical conversions of the enamines obtained have been studied, particularly leading to derivatives of 2-(cyanonitromethylene)imidazoline and -hexahydropyrimidine, and also to derivatives of N, N′-bisvinylpiperazine and 7 methylene-1, 4-diazabicyclo(2.2. 1 ]heptane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. A. Makarov, A. L. Sedov, M. P. Nemeryuk N. P. Solov'eva, and T. S. Safonova, Khim. Geterotsikl. Soedin., No. 7, 976 (1994).

  2. M. P. Nemeryuk, A. L Sedov, V. A. Makarov, N. P. Solov'eva, and T. S. Safonova, Khim. Geterotsikl. Soedin., No. 7, 999 (1991).

  3. J. Clark I. Gelling, and G. Noath, J. Chem. Soc., Chem. Commun, No. 17, 859 (1967).

  4. J. Clark, I. Gelling, I. W. Southon, and M. S. Morton, J. Chem. Soc. C, No. 3, 494 (1970).

  5. J. Clark M. Curphey, and I. W. Southon, J. Chem. Soc., Perkin Trans. 1, No. 14, 1611 (1974).

  6. V. G. Granik, S. S. Kiselev, N. P. Solov'eva, I. V. Persianova, M. K. Polievktov, and Yu. N. Sheinker, Khim. Geterotsikl. Soedin., No. 3. 344 (1980).

  7. S. Rajappa and B. G. Advani, Indian. J. Chem.,15, 890 (1977)

    Google Scholar 

  8. V. G. Granik, A. M. Zhidkova, R. G. Glushkov, I. V. Persianova, E. N. Peresleni, A. R. Engoyan, and Yu. N. Sheinker, Khim. Geterotsikl. Soedin., No. 9, 1220 (1974).

  9. V. G. Granik, A. M. Zhidkova, and R. G. Glushkov, Usp. Khim.,46, 685 (1977).

    Google Scholar 

  10. V. G. Granik, N. B. Marchenko, E. O. Sochneva, T. F. Vlasova, A. B. Grigor'ev, M. K. Polievktov, and R. G. Glushkov, Khim. Geterotsikl. Soedin., No. 11, 1506 (1976).

  11. V. G. Granik, E. N. Dozorova, N. B. Marchenko, L. I. Budanova, V. A. Kuzovkin, and R. G. Glushkov, Khim.-farm. Zh., No. 10, 1249 (1987).

  12. J. Clark, B. Parvizi, and I. W. Southon, J. Chem. Soc. Perkin Trans. 1, 125 (1976).

    Google Scholar 

Download references

Authors
  1. V. A. Makarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Sedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. S. Anisimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Granik
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Center for Drug Chemistry, All-Russian Chemical and Pharmaceutical Research Institute, Moscow 119815. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 811–820, June, 1996. Original article submitted February 6, 1996.

For Part 1, see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makarov, V.A., Sedov, A.L., Anisimova, O.S. et al. Highly polarized enamines. 2. Synthesis and investigation of the further amination of derivatives of α,α-DIAMINO-β-cyano-β-nitroethylene. Chem Heterocycl Compd 32, 699–707 (1996). https://doi.org/10.1007/BF01164870

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01164870

Keywords

Search

Navigation