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Synthesis and structure of [CpFe(CO){(Ph2P)2NlNMe2}] [I]-CH2Cl2

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Abstract

C32H31FeIN2OP2-[CH2Cl2],1, monoclinicP21/c,a=14.134(3),b=9.496(3),c=26.272(6) Å,β=90.92(2)°,Z=4,D c=1.49 g cm−3,R=0.044,R w=0.048, GOF=0.84. Interaction of the hydrazinophosphine Me2NN(PPh2)2 with cyclopentdienyliron dicarbonyl iodide in THF yields compound1 as the sole phosphorous containing species (by31P{1H} NMR). The structure of1 was inferred on the basis of spectroscopic data and solubility characteristics and confirmed via X-ray diffraction.

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Author notes

  1. S. G. Bott

    Present address: Department of Chemistry, University of North Texas, 76203, Denton, Texas

Authors and Affiliations

  1. Department of Chemistry, University of Texas at Arlington, 76019, Arlington, Texas

    C. J. Harlan & T. C. Wright

  2. Department of Chemistry, University of Alabama, 35487, Tuscaloosa, Alabama

    S. G. Bott & J. L. Atwood

Authors
  1. C. J. Harlan
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  2. T. C. Wright
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  3. S. G. Bott
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  4. J. L. Atwood
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Harlan, C.J., Wright, T.C., Bott, S.G. et al. Synthesis and structure of [CpFe(CO){(Ph2P)2NlNMe2}] [I]-CH2Cl2 . Journal of Crystallographic and Spectroscopic Research 22, 91–94 (1992). https://doi.org/10.1007/BF01161369

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  • DOI: https://doi.org/10.1007/BF01161369

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