Abstract
The compound has been characterized by X-ray crystal structure determination, Mössbauer and i.r. spectroscopy. It crystallizes in the monoclinic space groupP2 1 /c (No. 14) witha=24.228(4),b=8.335(2),c=23.975(4) Å,β=117.83(3)° andZ=8. Least-squares refinement on 3749 observed reflections gave finalR=0.034 (R w=0.037). The compound is constituted by [(C6H5)SbCl4OMe]− anions andphenH+cations. The coordination polyhedron about Sb is an octahedron (Sb-Cl 2.416(3), Sb-O 1.962(7) and Sb-C 2.138(9) Å). The whole structure is characterized by two short contacts (O(1)⋯N(2) 2.76(1) O(2)⋯N(4) 2.75(1) Å) involving the methoxy oxygens of the two independent anionic units [(C6H5)SbCl4OMe]− and two nitrogens of the two independent phenanthrolinium moieties.
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Alonzo, G., Bertazzi, N., Bombieri, G. et al. Synthesis, infrared and Mössbauer characterization and X-ray crystal structure of 1,10-phenanthrolinium tetrachloromethoxy phenylantimonate(V). Journal of Crystallographic and Spectroscopic Research 21, 635–640 (1991). https://doi.org/10.1007/BF01161087
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DOI: https://doi.org/10.1007/BF01161087