Skip to main content
SpringerLink
Log in

Crystal structure of bis-(thiophene-2-carboxaldehyde-4-phenyl-thiosemicarbazonato)-palladium(II)

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

The structure of bis-(thiophene-2-carboxaldehyde-4-phenyl-thiosemicarbazonato)-palladium(II) has been established by X-ray crystallography. C24H20N6S4Pd is monoclinic, space groupP21/a (No. 14). Unit-cell parametersa=9.112(1),b=14.494(2),c=10.194(1) Å, andβ=111.88(1)°;V=1249.3(5) Å3,M r=627.14,Z=2,D x=1.67 cm−3,F(000)=632,T=293 K,R=0.053 for 1254 observed reflections. Two sulfurs and two nitrogens are involved in planar coordination with the palladium. A five-membered thiophene ring is almost parallel to this coordination plane while the phenyl ring makes an angle of 31° with it.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Anbei, J., Kriiger, C., and Pfeil, B. (1987)Acta Crystallogr. C 43, 2334–2338.

    Google Scholar 

  • Clark, G. R., and Orbell, J. D. (1981)J. Organomet. Chem. 215, 121–129.

    Google Scholar 

  • Coghi, L., Manotti Lanfredi, A. M., and Tiripicchio, A. (1976)J. Chem. Soc. Perkin Trans. 2, 1808–1810.

    Google Scholar 

  • Gantzel, P. K., Sparks, R. A., and Trueblood, K. N. (1961)Lals, a program for the fullmatrix refinement of positional and thermal parameters and scale factors. (Univ. of California).

  • Gray, L. R., Gulliver, D. J., Levason, W., and Webster, M. (1983)Acta Crystallogr. C 39, 877–879.

    Google Scholar 

  • Hansen, F., and Hazell, R. G. (1969)Acta Chem. Scand. 23, 1359–1366.

    Google Scholar 

  • International Tables for X-ray Crystallography (1974) Vol. IV (Kynoch Press, Birmingham).

  • Iwasaki, F., and Kin-Ya-Akiba (1987)Acta Crystallogr. C 43, 2338–2340.

    Google Scholar 

  • Kubiak, M., Allain, A., Jezowska-Trzebiatowska, B., Glowiak, T., and Kozlowski, H. (1980)Acta Crystallogr. B 36, 2246–2250.

    Google Scholar 

  • Motherwell, W. D. S., and Clegg, W. (1978)Pluto-78. Program for plotting molecular crystal structures. (Univ. of Cambridge, England).

    Google Scholar 

  • Restivo, R., and Palenik, G. J. (1970)Acta Crystallogr. B 26, 1397–1402.

    Google Scholar 

  • Sonano-Garcia, M., Toscano, R. A., Valdes-Martinez, J., and Juan M. Fernandez, G. (1985)Acta Crystallogr. C 41, 498–500.

    Google Scholar 

  • Tavale, S. S., and Guru Row, T. N. (1986)Proc. Ind. Acad. Sci. 97, 209–211.

    Google Scholar 

  • Umapathy, P., Budhkar, A. P., and Dorai, C. S. (1986)J. Ind. Chem. Soc. 63, 714–721.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Division of Biochemical Sciences, India

    C. G. Suresh & Asmita Deshpande

  2. Physical and Structural Chemistry Division, India

    S. S. Tavale

  3. Inorganic Chemistry Division National Chemical Laboratory, 411008, Pune, India

    P. Umapathy

Authors
  1. C. G. Suresh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Asmita Deshpande
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. S. Tavale
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. Umapathy
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

NCL Communication No. 4969.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Suresh, C.G., Deshpande, A., Tavale, S.S. et al. Crystal structure of bis-(thiophene-2-carboxaldehyde-4-phenyl-thiosemicarbazonato)-palladium(II). Journal of Crystallographic and Spectroscopic Research 21, 485–487 (1991). https://doi.org/10.1007/BF01160663

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01160663

Keywords

Search

Navigation