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Investigation of the oxidation of methane with the aid of labeled atoms

Communication 2. Mechanism of the formation of carbon dioxide

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It was shown by a kinetic method that carbon, monoxide is not the sole precursor of carbon dioxide in the oxidation of methane.

  2. 2.

    Comparison of rates of accumulation of C02 with the rate of its formation from CO shows that only about 25% of the C02 is formed by the oxidation of CO.

  3. 3.

    By the reduction of C14O2 with zinc, C140 of high activity was obtained in 98% yield.

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Literature cited

  1. L. N. Antonova, V. A. Kuzmin, R. I. Moshkina, A. B. Nalbandyan, M. B. Neiman, and G. I. Fekllsov, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1955, 789.

  2. M. B. Neiman, Chem. Sci. and Ind, No. 1, 1 (1956).

  3. Technical Encyclopedia 25, 731, 1934.

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Authors and Affiliations

  1. I. I. Lenin All-Union Electrotechnics Institute, USSR

    R. I. Moshkina, A. B. Nalbandyan, M. B. Neiman & G. I. Feklisov

Authors
  1. R. I. Moshkina
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  2. A. B. Nalbandyan
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  3. M. B. Neiman
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  4. G. I. Feklisov
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Moshkina, R.I., Nalbandyan, A.B., Neiman, M.B. et al. Investigation of the oxidation of methane with the aid of labeled atoms. Russ Chem Bull 6, 821–825 (1957). https://doi.org/10.1007/BF01160224

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  • DOI: https://doi.org/10.1007/BF01160224

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