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Comb polysiloxanes with ω-hydroxyoligo(oxyethylene) side chains

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Summary

Comb-like polysiloxanes with pendant chains of the type (CH2)3(OCH2 CH2)nOH (n=0, 8 or 15) were synthesized by hydrosilylation of poly(methylsiloxane) with the corresponding monoallyl glycols in which the hydroxyl group was protected with tetrahydropyran. The polymers were characterized by1H and29Si NMR, and by GPC and DSC. A considerable fraction of small cycles is formed for the n=o compound during the deprotection reaction. Side chain crystallization occurs but is slower than for polymers containing side chains with terminal methoxy groups.

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References

  1. D. Fish, I.M. Khan and J. Smid, Makromol. Chem. Rapid Commun.7, 115 (1986).

    Google Scholar 

  2. D. Fish, I.M. Khan, E. Wu and J. Smid, Brit. Polym. J.20, 281 (1988).

    Google Scholar 

  3. I.M. Khan, Y. Yuan, D. Fish, E Wu and J. Smid, Macromolecules, in press.

  4. R. Spindler and D.F. Shriver, J. Amer. Chem. Soc.110. 3036 (1988).

    Google Scholar 

  5. P.G. Hall, G.R. Davies, J.E. McIntyre, I.M. Ward, D.J. Bannister and K.M.F. LeBrocas, Polym. Commun.27, 98 (1986).

    Google Scholar 

  6. G.B. Zhou, I.M. Khan and J. Smid, Polym. Commun., in press.

  7. L.C. Hardy and D.F. Shriver, J. Amer. Chem. Soc.107. 3823 (1985).

    Google Scholar 

  8. D.J. Bannister, G.R. Davies, I.M. Ward and J.F. McIntire, Polymer,25, 1291 (1984).

    Google Scholar 

  9. J.F. LeNest, A. Gandini, H. Cheradame and J.P. Cohen Addad, Polymer Commun.28, 302 (1987).

    Google Scholar 

  10. Y. Kawakamie, T. Aoki and Y. Yamashita, Polym. Bull.18, 473 (1987).

    Google Scholar 

  11. C.L. Lee, J. Smid and M. Szwarc, J. Phys. Chem.66, 904 (1962).

    Google Scholar 

  12. M. Miyashita, A. Yoshikoshi and P.A. Grieco, J. Org. Chem.42, 3772 (1977).

    Google Scholar 

  13. P.V. Wright in “Ring Opening Polymerization”, ed. by K.J. Ivin and T. Saegusa, Elsevier, New York (1984), Vol. 2, p. 1058.

    Google Scholar 

  14. E.A. Williams in “Annual Reports on NMR Spectroscopy”, G.A. Webb, Ed. (1979), Vol. 9, p. 221.

  15. D. Fish, I.M. Khan and J. Smid, Polym. Prepr.29, (2), 1988, (in press).

  16. I. Nwankwo, D.W. Xia and J. Smid, J. Polym. Sci., Polym. Phys. Ed.26, 581 (1988).

    Google Scholar 

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Authors and Affiliations

  1. Polymer Research Institute, Chemistry Department, College of Environmental Science and Forestry, State University of New York, 13210, Syracuse, NY, USA

    E. Wu, Ishrat M. Khan & Johannes Smld

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  1. E. Wu
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  2. Ishrat M. Khan
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  3. Johannes Smld
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Wu, E., Khan, I.M. & Smld, J. Comb polysiloxanes with ω-hydroxyoligo(oxyethylene) side chains. Polymer Bulletin 20, 455–461 (1988). https://doi.org/10.1007/BF01153437

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  • DOI: https://doi.org/10.1007/BF01153437

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