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Synthesis of telehelic oligodimethylsiloxanes with 4-carboxypyrrolidone fragments: rheological and thermal properties

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Abstract

Telehelic oligodimethylsiloxanes containing 4-carboxypyrrolidone fragments were synthesized by the reactions of oligodimethylsiloxanes bearing terminal 3-aminopropyl groups with itaconic acid. The thermal and rheological properties of the obtained polymers were studied. The activation energies of viscous flow of the oligomers obtained and the previously synthesized oligodimethylsiloxanes containing terminal fragments of undecenoic or benzoic acid are compared.

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Authors and Affiliations

  1. N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    V. V. Gorodov, A. V. Bakirov, D. I. Shragin, V. D. Myakushev, S. N. Chvalun & A. M. Muzafarov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. V. Gorodov, M. I. Buzin, V. G. Vasil´ev, D. I. Shragin, V. S. Papkov & A. M. Muzafarov

  3. Research Center “Kurchatov Institute,”, 1 pl. Akad. Kurchatova, 123182, Moscow, Russian Federation

    A. V. Bakirov & S. N. Chvalun

  4. V. I. Lenin Moscow Pedagogical State University, 1 ul. Malaya Pirogovskaya, 119992, Moscow, Russian Federation

    M. I. Buzin

Authors
  1. V. V. Gorodov
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  2. A. V. Bakirov
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  3. M. I. Buzin
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  4. V. G. Vasil´ev
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  5. D. I. Shragin
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  6. V. D. Myakushev
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  7. V. S. Papkov
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  8. S. N. Chvalun
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  9. A. M. Muzafarov
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Corresponding author

Correspondence to V. V. Gorodov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2282–2289, December, 2018.

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Gorodov, V.V., Bakirov, A.V., Buzin, M.I. et al. Synthesis of telehelic oligodimethylsiloxanes with 4-carboxypyrrolidone fragments: rheological and thermal properties. Russ Chem Bull 67, 2282–2289 (2018). https://doi.org/10.1007/s11172-018-2371-5

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  • DOI: https://doi.org/10.1007/s11172-018-2371-5

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