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Reactions of organometallic compounds and groups with sterically hindered o-quinones

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have suggested a scheme for the one-electron oxidation of group II OMC by substituted o-quinones.

  2. 2.

    The influence of the nature of the radicals R attached to mercury on the hyperfine coupling constantaHg is related to the changes in the geometric configuration of the

    unit caused by changes in the bulk of the substituent R.

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Literature cited

  1. G. A. Razuvaev, G. A. Abakumov, E. S. Klimov, E. N. Gladyshev, and P. Ya. Bayushkin, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1128.

  2. G. A. Abakumov, E. N. Gladyshev, N. S. Vyazankin, G. A. Razuvaev, P. Ya. Bayushkin, and V. A. Muraev, J. Organomet. Chem.,64, 327 (1974).

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  3. Chemist's Handbook [in Russian], Vol. 3, Khimiya (1964), p. 957.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 176–180, January, 1978.

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Gladyshev, E.N., Bayushkin, P.Y., Abakumov, G.A. et al. Reactions of organometallic compounds and groups with sterically hindered o-quinones. Russ Chem Bull 27, 154–156 (1978). https://doi.org/10.1007/BF01153229

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  • DOI: https://doi.org/10.1007/BF01153229

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