Abstract
We have investigated the possibility of pyrrole oligomerization within zeolite channels in acid zeolites containing Fe3+ to study the action of acid and one-electron oxidation polymerization mechanisms together. We also indicate the possibility of preparing materials with electrical conductivities varying within a wide range based on the combined adsorption of pyrrole and water in acid zeolites. Further it is shown that pyrrole polymerization is possible at the surface of amorphous aluminosilicates with the consequent generation of a hydrophobic surface.
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H. Shirakawa, E. Louis, A. Macdiarmid, C. Chiang andA. J. Heeger,J. Chem. Soc. Chem. Commun. (1977) 758.
G. Tourillon andF. Garnier,J. Electroanal. Chem. 135 (1982) 173.
A. G. Macdiarmid, J. C. Chiang, M. Halpern, W. S. Huang, S. L. Mu, N. D. L. Somasiri, W. Wu andS. Yaniger,Mol. Cryst. Liq. Cryst. 121 (1985) 173.
F. Garnier,Angew. Chem. 101 (1989) 529.
G. A. Ozin, A. Kuperman andA. Stein,ibid. 101 (1989) 3731.
P. Enzel andT. Bein,J. Phys. Chem. 93 (1989) 6270.
J. V. Caspar, V. Ramamurthy andD. Corbin,J. Amer. Chem. Soc. 113 (1991) 600.
D. R. Rolison,Chem. Rev. 90 (1990) 867.
P. Enzel andT. Bein.J. Chem. Soc. Chem. Commun. (1989) 1326.
P. Bein andT. Enzel,Synth. Met. 29 (1989) 163.
T. H. Chao andH. A. Erf,J. Catal. 100 (1986) 492.
T. Bein andP. Enzel,Angew. Chem. 28 (1989) 1692.
R. Roque, C. Diaz, E. Reguera, J. Fundora, L. Lopez andM. Hernandez,Zeolites 10 (1990) 685.
A. Montes, R. Roque andE. D. Shchukin,J. Thermal Anal. 31 (1986) 41.
C. De Las Pozas, C. Diaz, E. Reguera andR. Roque,J. Solid State Chem. 93 (1991).
R. Roque andA. Montes,J. Thermal Anal. 31 (1986).
M. Carreras, R. Roque andC. De Las Pozas,ibid. 32 (1987) 1271.
R. Roque andM. Hernandez,ibid. 36 (1990) 1025.
O. Vigil, M. Hernandez, J. Fundora, J. De oñate andR. Roque, in preparation.
R. Roque andM. Hernandez,J. Thermal Anal. 36 (1990) 2024.
O. Vigil, M. Hernandez, J. Fundora, H. Villavicencio andR. Roque,J. Mater. Sci. Lett. in press.
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Roque, R., de Onate, J., Reguera, E. et al. Pyrrole oligomerization within H-Fe-FAU zeolite. J Mater Sci 28, 2321–2323 (1993). https://doi.org/10.1007/BF01151660
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DOI: https://doi.org/10.1007/BF01151660