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The potential strain energy of a polymer molecule in nonlinear approximation

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Polymer Mechanics Aims and scope

Abstract

The intermolecular interaction mechanism is analyzed, and the results are used to derive a general semiempirical formula for the strain energy of a helical polymer molecule in nonlinear approximation. Formulas are given for the homogeneous straining of specific polymers. The relationship between the elastic constants of the molecule and the final strain is computed.

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References

  1. E. B. Wilson, J. Chem. Phys.,7, 1047, 1939;9, 76, 1941.

    Google Scholar 

  2. T. Miyozawa, J. Chem. Phys.,35, 693, 1961.

    Google Scholar 

  3. H. Tadokoro, M. Kobayashi, M. Ukita, K. Yasufuki, and Murahashi, J. Chem. Phys.,42, 1432, 1965.

    Google Scholar 

  4. L. A. Gribov, Optika i spektroskopiya,16, 216, 1964.

    Google Scholar 

  5. P. P. Kobeko, Amorphous Substances [in Russian], Moscow-Leningrad, 1952.

  6. A. I. Gubanov and A. D. Chevychelov, FTT,4, 928, 1962.

    Google Scholar 

  7. H. Hellmann, Einfuhrung in die Quantenchemie [Russian translation], Moscow-Leningrad, 1937.

  8. M. V. Vol'kenshtein, Configurational Statistics of Polymer Chains [in Russian], Moscow-Leningrad, 1959.

  9. S. E. Bresler and Ya. I. Frenkel, ZhETF,9, 1094, 1939.

    Google Scholar 

  10. A. I. Kitaigorodskii, DAN,137, 116, 1961.

    Google Scholar 

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Mekhanika Polimerov, Vol. 3, No. 4, pp. 608–614, 1967

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Gubanov, A.I. The potential strain energy of a polymer molecule in nonlinear approximation. Polymer Mechanics 3, 408–411 (1967). https://doi.org/10.1007/BF01150953

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  • DOI: https://doi.org/10.1007/BF01150953

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