Skip to main content
SpringerLink
Log in

Synthese neuer Aminofluorsilane, sowie Alkoxylierung von Bis (trimethylsilyl)-amino-fluorsilanen

Syntheses of new aminofluorosilanes and alkoxylation of [bis(trimethylsilyl)amino]-fluorosilanes

4. Mitt. über Silicium-Stickstoff-Fluor-Verbindungen

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The reaction of aminofluorsilanes of the type (R=H,F) (Me 3Si)2N−SiF2R with two moles of ammonia, or of a mono- or dialkylamine, yields the corresponding amino-compounds, e.g. (Me 3Si)2N−Si(F)R−NH2, (Me 3Si)2N−Si(F)R−NHR′ and (Me 3Si)2N−Si(F)R−NR2′ (R′=Me, Et). Analogous products are obtained by reaction of the aminofluorosilanes with lithium salts of amines with bulky organic substituents in a 1 : 1 molar ratio. Alkoxy- and aryloxyaminofluorosilanes are prepared by the reaction of sodium alcoholates and sodium phenolate with (Me 3Si)2N−Si(F2)R (R=H, C2H3, C2H5, C6H5).

The i.r.-, mass-,1H- and19F-NMR spectra of the above compounds are reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. U. Wannagat, F. Höfler undH. Bürger, Mh. Chem.99, 1186 (1968).

    Google Scholar 

  2. J. J. Harris undB. Rudner, J. inorg. nucl. Chem.34, 75 (1972).

    Google Scholar 

  3. J. J. Mosconi undA. G. MacDiarmid, Chem. Commun.1965, 307.

  4. U. Wannagat, H. Bürger undF. Höfler, Mh. Chem.99, 1198 (1968).

    Google Scholar 

  5. U. Wannagat undH. Bürger, Angew. Chem.76, 497 (1964).

    Google Scholar 

  6. U. Wannagat, K. Behmel undH. Bürger, Chem. Ber.97, 2029 (1964).

    Google Scholar 

  7. U. Klingebiel undA. Meller, Chem. Ber.108, 155 (1975).

    Google Scholar 

  8. U. Klingebiel undA. Meller, J. organomet. Chem. (im Druck).

  9. R. O. Sauer, J. Amer. Chem. Soc.66, 1707 (1944).

    Google Scholar 

  10. R. Fessenden undJ. S. Fessenden, Chem. Rev.61, 361 (1961).

    Google Scholar 

  11. H. Niederprüm, Angew. Chem.75, 165 (1963).

    Google Scholar 

  12. U. Wannagat undP. Geymayer, Mh. Chem.95, 1095 (1964).

    Google Scholar 

  13. U. Wannagat undH. Bürger, Z. anorg. allg. Chem.326, 309 (1964).

    Google Scholar 

  14. H. Bürger undU. Wannagat, Z. anorg. allg. Chem.319, 244 (1963).

    Google Scholar 

  15. W. E. Weibrecht undE. Rochow, J. organomet. Chem.5, 520 (1966).

    Google Scholar 

  16. U. Klingebiel, D. Fischer undA. Meller, J. organomet. Chem.85, 141 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstraße 4, D-3400, Göttingen, Bundesrepublik Deutschland

    Uwe Klingebiel, Dietrich Fischer &  Anton Meller

Authors
  1. Uwe Klingebiel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dietrich Fischer
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Anton Meller
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

1. Mitt.: Chem. Ber.108, 155, 1975; 2. Mitt.: J. Organometal. Chem.85, 141, 1975; 3. Mitt.: J. Organometal. Chem., im Druck.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Klingebiel, U., Fischer, D. & Meller, A. Synthese neuer Aminofluorsilane, sowie Alkoxylierung von Bis (trimethylsilyl)-amino-fluorsilanen. Monatshefte für Chemie 106, 459–471 (1975). https://doi.org/10.1007/BF01150527

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01150527

Search

Navigation