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Reaction of oxochloroalkenes with phosphorous acid esters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

2-Qxo-3-methyl-5-chloro-3-hexene and trans-2-oxo-5-chloro-3-heptene, adequate low-molecular-weight models of labile carbonylallyl groups in poly(vinyl chloride) macromolecules, were synthesized. Tributyl phosphite reacts with the model compounds at the oxovinylene fragment via a step of formation of intermediate phosphorane structures, which are converted to stable ketophosphonates during heating.

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Authors and Affiliations

  1. S. M. Kirov Kazan Chemical-Technological Institute, USSR

    N. A. Mukmeneva, E. N. Cherezova, L. N. Yamalieva, S. V. Kolesov, K. S. Minsker & P. A. Kirpichnikov

  2. Bashkir State University, Ufa

    N. A. Mukmeneva, E. N. Cherezova, L. N. Yamalieva, S. V. Kolesov, K. S. Minsker & P. A. Kirpichnikov

Authors
  1. N. A. Mukmeneva
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  2. E. N. Cherezova
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  3. L. N. Yamalieva
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  4. S. V. Kolesov
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  5. K. S. Minsker
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  6. P. A. Kirpichnikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1106–1108, May, 1985.

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Mukmeneva, N.A., Cherezova, E.N., Yamalieva, L.N. et al. Reaction of oxochloroalkenes with phosphorous acid esters. Russ Chem Bull 34, 1009–1011 (1985). https://doi.org/10.1007/BF01142792

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  • DOI: https://doi.org/10.1007/BF01142792

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