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127I NQR spectra in iodonium compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    For a series of iodonium compounds of the Ar2IX type, it has been found that the127I NQR parameters — the quadrupole coupling constant e2Qqzz, the asymmetry parameter η, and the frequency field constant ϖv/ϖEz -vary regularly with the nature of the cation and the character of substitution in the ring.

  2. 2.

    Strengthening of the coordination interactions leads to a sharp jump in the frequency field constant ∂v/∂Ez and a significant change in the asymmetry parameter η.

  3. 3.

    For this series of compounds, a linear, correlation has been established between the values of e2Qqzz and η.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    G. K. Semin, S. I. Gushchin, S. A. Petukhov, V. V. Saatsazov, T. L. Khotsyanova, I. N. Lisichkina, L. D. Egorova & T. P. Tolstaya

Authors
  1. G. K. Semin
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  2. S. I. Gushchin
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  3. S. A. Petukhov
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  4. V. V. Saatsazov
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  5. T. L. Khotsyanova
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  6. I. N. Lisichkina
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  7. L. D. Egorova
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  8. T. P. Tolstaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1002–1007, May, 1985.

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Semin, G.K., Gushchin, S.I., Petukhov, S.A. et al. 127I NQR spectra in iodonium compounds. Russ Chem Bull 34, 913–917 (1985). https://doi.org/10.1007/BF01142774

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  • DOI: https://doi.org/10.1007/BF01142774

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