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Primary aliphatic alcohols and simple ethers as carriers of acids in ionic hydrogenation of olefins

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the two-phase system H2SO4-CH2C12 ionic hydrogenation of olefins takes place in the organic layer.

  2. 2.

    Simple ethers, starting with dibutyl and higher, and primary alcohols starting with n-hexyl and higher are active carriers of sulfuric acid into the organic phase. The effectiveness of these carriers depends on their concentrations and the volume ratio of the acid and organic phases.

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Literature cited

  1. G. D. Kolomnikova, M. I. Kalinkin, Z. N. Parnes, and D. N. Kursanov, Dokl. Akad. Nauk SSSR,265, 352 (1982).

    Google Scholar 

  2. I. V. Berezin, K. Martinek, and A. K. Yatsimirskii, Usp. Khim.,42, 172 (1973).

    Google Scholar 

  3. D. Landini, F. Montanari, and F. Rolla, Synthesis, 771 (1978).

  4. C. M. Starks and C. Liotta, Phase Transfer Catalysis, Academic Press, New York (1978), p. 60.

    Google Scholar 

  5. A. A. Rudnitskaya, V. D. Maiorov, M. B. Librovich, and Yu. A. Fialkov, Izv. Akad. Nauk SSSR, Ser. Khim., 960 (1981).

  6. R. Benkeser, H. Landssman, and D. Foster, J. Am. Chem. Soc.,74, 648 (1952).

    Google Scholar 

  7. R. A. W. Johnstone and M. E. Rose, Tetrahedron,35, 2169 (1979).

    Google Scholar 

  8. V. G. Linovich, T. G. Laperdina, P. E. Latysheva, and G. A. Kalabin, Zh. Obshch. Khim.,52, 284 (1982).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    G. D. Kolomnikova, M. I. Kalinkin, S. A. Goloshchapova, Z. N. Parnes & D. N. Kursanov

Authors
  1. G. D. Kolomnikova
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  2. M. I. Kalinkin
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  3. S. A. Goloshchapova
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  4. Z. N. Parnes
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  5. D. N. Kursanov
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1086–1089, May, 1984.

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Kolomnikova, G.D., Kalinkin, M.I., Goloshchapova, S.A. et al. Primary aliphatic alcohols and simple ethers as carriers of acids in ionic hydrogenation of olefins. Russ Chem Bull 33, 997–1000 (1984). https://doi.org/10.1007/BF01141712

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  • DOI: https://doi.org/10.1007/BF01141712

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